INTRODUCTION TO MARCUS THEORY OF ELECTRON TRANSFER REACTIONS

This book, with a foreword from Nobel Laureate Rudolph A Marcus, aims at introducing the reader to the Marcus theory of electron transfer reactions from a reading of excerpts of Marcus' papers. Notes from the author may be of help to the student or the beginner. Marcus' notes at the end of each paper, with his comments and remarks, are an invaluable supplement to his articles for students and scholars in the field of electron transfer reactions.

Contents:

• Introduction
• Foundations of the Theory, Its First Formulation
• Extensions, Electron Transfer at Electrodes, Applications
• Theory of Electrochemical Electron Transfer
• Statistical Mechanical Theory of Electron Transfer, Equivalent Equilibrium Distribution, Reaction Coordinate for ET, Inverted Free Energy Effect, Interactions in Polar Media
• Unified General Theory of Electron Transfer Reactions
• Theory of Electron Transfer Reactions of Solvated Electrons and of Chemiluminescent Electron Transfer Reactions
• Rate Constants, Barriers, and Brønsted Slopes, Electron Transfer at Electrodes and in Solution: Theory versus Experiment–Electrode Reactions of Organic Compounds
• Activated-Complex Theory, Application to Electron Transfer Reactions. Marcus' Notes on Electron Transfer, on Proton Transfer and on Electrode Kinetics
• Unusual Activation Parameters, Electron and Nuclear Tunneling, Mechanisms of Charge Separation, Spin Exchange and Electron Transfer in Photosynthesis; Electron Transfer versus Proton Transfer at Electrodes and in Solution, Hydrogen Evolution, Quantum Effects, Classical and Semiclassical Calculations of Electron Transfer Rates
• Mixed Reaction-Diffusion Rates, Quantum Effects in the Inverted Region, Frequency Factor in Electron Transfer: ItsRole in the Highly ExothermicRegime, Highly Exothermic Electron Transfer, Electron and Proton Transfer, Nonadiabatic Processes, Quantum-like and Classical-like Coordinates, Applications to Nonadiabatic Electron Transfers
• Entropic, Electrolyte, and Orientation Effects in Electron Transfer, Electron Transfer in Chemistry and Biology, Application of Electron Transfer to Systems of Biological Interest, Barriers for Thermal and Optical Electron Transfer in Solution, Semiclassical Model for Orientation Effects in Electron Transfer, Orientation Effects on Electron Transfer between Porphyrins
• Dynamical Effects in Electron Transfer Reactions, Dielectric Relaxation and Intramolecular Electron Transfer, Solvent Dynamics, and Vibrational Effects in Electron Transfer

Readership: Chemistry students and researchers in the field of electron transfer reactions.

'Looking for an exciting and comprehensive understanding of electron transfer kinetics? Look no further than Professor Francesco's two-volume collection! Despite dating back to the 1950s, the formalisation of redox dynamics remains a complex and challenging topic. However, Professor Francesco, using the historical analytical approach, brilliantly captures the essence and genius of Nobel laureate R. Marcus's seminal work, providing a unified and accessible understanding of this fascinating and rapidly evolving field. This work is a true masterpiece and an absolute must-read for anyone interested in this important area of study. Get ready to be blown away!' - Prof Olivier FONTAINEDirector of Molecular Electrochemistry for Energy laboratory, VistecMember of Institut Universitaire de France

'Electron transfer reactions are pivotal in essential processes in nature, as well as in technologies such as energy and chemical production, and the functioning of electronic devices. 'Introduction to Marcus Theory of Electron Transfer Reactions' by Francesco Di Giacomo is an exceptional book that masterfully manages to make the complex field of Marcus theory accessible to both seasoned scientists and non-specialists alike through excellent examples showing the core principles as well as diverse, relevant applications. The book breaks down the intricacies of Marcus theory, shows its connections to other contemporary theories and demonstrates its profound implications in a manner that is both comprehensive and enlightening. As Prof. Marcus himself said 'Being exposed to theory, stimulated by a basic love of concepts and mathematics, was a marvellous experience.' and if you believe this is still true, you will enjoy and appreciate this book!' - Prof Robert ForsterDublin City University

Key Features:

• The book differs from other books on the theory of ET because it explains Marcus' theory through a simplified presentation of his papers with simple remarks from the author and with Marcus' notes and comments on his papers